Oh yes, absolutely. In fact Trezor uses two signature algorithms for their firmwares, pre and post quamtum precisely for the case that the post quatum algo ends being unsafe. Unfortunately I don't remember the details. I hope some of them come and comment. ping @Hynek
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Yes that's a very good point. I remember now that DJB is a strong advocate for exactly this.
Notice though how in performance critical applications, using even more space and time to do this is going to be ... ouch.
The Trezor Safe 7 boardloader uses a hybrid scheme:
Signed with both SLH-DSA and ECDSA (secp256r1).
The ECDSA signature also signs the SLH-DSA signature.
It is described in more technical details here 
Going quantum: our choices for Trezor Safe 7’s quantum readiness
Trezor Safe 7 is quantum-ready from the core. Discover the cryptographic standards, hybrid verification, and authenticity measures that make it sec...