Will save this conversation and then ping here when is time to test it. Don't think anyone here has implemented yet a nostr master key system as reference to learn from them, so will see how an implementation can look like. At least a nostr key rotating a PGP key seems fairly straightforward.

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You can build a signing chain, but it collapses the separation. If the nsec signs each new PGP key, the Nostr key becomes a permanent root authority and a single compromise breaks the entire lifecycle. The whole point of coordinating two systems is to avoid that failure mode. With deterministic epochs, clients can verify rotation without deputizing nsec as a god key. Once you have a stable root, rotation is just schedule + client support. Everything else is implementation detail.