Yes, they're less desirable, and are therefore perceived as less valuable, but they're sometimes more essential.
One reason some things are free is because it is considered overly burdensome or even cruel to demand pay for them, so that their provision becomes a "good work".
Sometimes they are free because the provider wants you to have it more than you would ever desire it. Then, they get something else out of it.
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air is pretty much in most situations an example of a non-economic good. it only has value in situations where the air has been polluted mostly. this would be an example of two uses in collision, burning coal and living near it are in conflict with each other so an economization is needed. either the plant cleans up its smoke stack or the people move, at the expense of the smoke stack.